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Brady B-492: Freezerbondz White Polyester Thermal Printable Label Stock

Brady B-492 Freezerbondz is a white polyester thermal transfer label stock with a white printable topcoat and a permanent acrylic adhesive, designed for laboratory identification such as vials, centrifuge tubes, test tubes, straws, and slides. It can be applied to frozen surfaces including glass and polypropylene stored in liquid nitrogen, but the sheet carries a footnote reading "Metal surfaces should be labeled at room temperature only." All testing described on the sheet was performed with the Brady Series R6400 ribbon, and the alternate Brady Series R4300 ribbon may only be used if chemical resistance to Ethanol, Toluene and Xylene is not required.

Material Composition
Polyester - white film with white thermal transfer printable topcoat, permanent acrylic adhesive
Adhesive System
Permanent Acrylic
Operating Temperature
-196°C to 110°C (-321°F to 230°F)
Total Thickness
3.2 mils (0.081 mm)
Brady B-492 Freezerbondz White Polyester Thermal Printable Label Stock industrial application photography
Figure 1: Brady B-492FreezerBondz™ Cryogenic Polyester adhering directly to frosted -196°C liquid nitrogen vialsField Application Photo
-196°C Cryo Storage

B-492 Application & Installation Blueprint

Cryogenic Laboratory Vial & Tube Label • Physical application tolerances and surface engineering
Industrial Fit Certified
B-492 real-world industrial application
Installed in real-world industrial environment
Deep Cryo Vial Labeling & Overlap Guide
1Apply label directly to room-temperature or frozen polypropylene cryo vials.
2Wrap label around circumference ensuring at least 1/8" overlap seam.
3Press firmly along overlap edge before plunging into liquid nitrogen vapor or -80°C deep freezers.
Engineering Tolerance: Engineered to withstand liquid nitrogen (-196°C / -320°F) and autoclaving (+121°C) without uncurling.
Substrate Compatibility & Adhesion Matrix
Polypropylene Cryovials & Conicals
LN2 Proof (5/5)
Eppendorf Microcentrifuge Tubes
LN2 Proof (5/5)
Glass Microscope Slides & Vials
Cryo Bond (5/5)
Polystyrene 96-Well Microplates
Cryo Bond (4.8/5)
Tested Environmental Survivability
-196°C Liquid Nitrogen LN2-80°C Ultra-Low Freezers+121°C Autoclave SteamDMSO & Bleach Reagents
Recommended Field & Shop Tools:
M210-LAB Portable Makeri5100 Benchtop PrinterR6400 Resin Ribbon

Orderable Part Numbers, Packaging & Distributor SKUs

Official Brady SKUs, roll dimensions, package quantities, list pricing, Grainger part numbers, and printer compatibility for B-492.

Popular B-492 Formats

Standard industrial rolls and die-cut sizes with unit cost breakdown
#1 Popular Choice
Standard Part
0.5 in H x 1 in W x 0.375 in Dia
Cartridge of 240 Labels
Roll / Pack Total:$74.99 USD
Normalized Unit Cost:$0.31/label
Material Area Cost:$0.62/sq in
Supported Hardware:
M510M511
Grainger
#2 Standard Format
Standard Part
0.5 in H x 1 in W
Cartridge of 180 Labels
Roll / Pack Total:$70.99 USD
Normalized Unit Cost:$0.39/label
Material Area Cost:$0.79/sq in
Supported Hardware:
M410M510M511
Grainger
#3 High Capacity
Standard Part
0.5 in H x 0.9 in W x 0.44 in Dia
Cartridge of 240 Labels
Roll / Pack Total:$74.99 USD
Normalized Unit Cost:$0.31/label
Material Area Cost:$0.69/sq in
Supported Hardware:
M510M511
Grainger
All 66 Orderable Part Numbers
Pricing: $42.49 – $1289.00 USD
Catalog SKUDimensionsPackaging / QtyList Price & Unit CostOrder MOQCompatible PrintersHardware & Related
M5-120-492Popular
UPC: 888434593219
0.5 in H x 1 in W x 0.375 in DiaCartridge of 240 Labels
$74.99 USD
$0.31/label ($31.25/100)
$0.62/sq in
1 CTR
Standard Order
M510M511
M4-131-492Popular
UPC: 888434592076
0.5 in H x 1 in WCartridge of 180 Labels
$70.99 USD
$0.39/label ($39.44/100)
$0.79/sq in
1 CTR
Standard Order
M410M510+1
M5-117-492Popular
UPC: 888434593226
0.5 in H x 0.9 in W x 0.44 in DiaCartridge of 240 Labels
$74.99 USD
$0.31/label ($31.25/100)
$0.69/sq in
1 CTR
Standard Order
M510M511
B33-59-492Popular
UPC: 662820969037
0.5 in H x 1 in WCartridge of 2500 Labels
$436.99 USD
$0.17/label ($17.48/100)
$0.35/sq in
1 ROL
Standard Order
BBP33i3300+2
M5-118-492Popular
UPC: 888434593202
0.375 in H x 1 in W x 0.375 in DiaCartridge of 240 Labels
$72.99 USD
$0.30/label ($30.41/100)
$0.81/sq in
1 CTR
Standard Order
M510M511
M5-156-492Popular
UPC: 888434593196
1 in H x 0.9 in WCartridge of 180 Labels
$76.99 USD
$0.43/label ($42.77/100)
$0.48/sq in
1 CTR
Standard Order
M510M511
UPC: 662820969402
0.5 in H x 1 in W x 0.375 in DiaCartridge of 1500 Labels
$143.99 USD
$0.096/label ($9.60/100)
$0.19/sq in
1 ROL
Standard Order
BBP33i3300+2
UPC: 662820803713
0.5 in H x 1 in WRoll of 2500 Labels
$257.99 USD
$0.10/label ($10.32/100)
$0.21/sq in
1 ROL
Standard Order
BBP11BBP12+1
UPC: 662820662662
0.5 in H x 1 in WPack of 2 Rolls
$874.99 USD
$0.087/label ($8.75/100)
$0.17/sq in
1 PAK
Standard Order
BBP81i5100+6
UPC: 662820662679
1 in H x 1 in WRoll of 3000 Labels
$349.99 USD
$0.12/label ($11.67/100)
$0.12/sq in
1 ROL
Standard Order
BBP81i5100+6
UPC: 662820969075
1 in H x 1 in WCartridge of 1900 Labels
$218.99 USD
$0.12/label ($11.53/100)
$0.12/sq in
1 ROL
Standard Order
BBP33i3300+2
UPC: 662820662747
0.5 in H x 1 in WRoll of 3000 Labels
$287.99 USD
$0.096/label ($9.60/100)
$0.19/sq in
1 ROL
Standard Order
BBP81i5100+6
UPC: 662820969228
0.5 in H x 1 in W x 0.44 in DiaCartridge of 1500 Labels
$143.99 USD
$0.096/label ($9.60/100)
$0.19/sq in
1 ROL
Standard Order
BBP33i3300+2
UPC: 662820662655
0.375 in H x 1 in WRoll of 3000 Labels
$224.99 USD
$0.075/label ($7.50/100)
$0.20/sq in
1 ROL
Standard Order
BBP81i5100+6
UPC: 662820915294
1 in H x 1 in WRoll of 2500 Labels
$290.99 USD
$0.12/label ($11.64/100)
$0.12/sq in
1 ROL
Standard Order
BBP11BBP12+1
Showing 1 to 15 of 66 parts
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Quality Assurance, Storage & Regulatory Compliance

Standardized engineering guidelines for warehouse storage, application temperature, and agency certifications.

Shelf Life & Warehouse Storage
Expected Shelf Life: 2 Years from receipt
Storage Temperature: Below 80°F (27°C)
Relative Humidity: 60% RH
Must be stored in original packaging in a climate-controlled warehouse.
Application vs Service Limits
Min Application Temp: 50°F (10°C)
Service Temp Range: -196°C to 110°C (-321°F to 230°F)
Full Cure / Dwell Time: 24 Hours (ASTM D1000)
Clean surface of oil/grease before bonding for maximum peel strength.
Agency Testing & File Directories
UL 969 / 2238: Non-approved variant
UL Directory
CSA C22.2: Not certified
CSA Directory
Environmental & Safety Standards
RoHS 3 Compliance:2011/65/EU (Pass 2015/863)
REACH Status:SVHC Free (<0.1% w/w)
CA Prop 65:Compliant Notice
Certificates of Conformance (CoC) available on order shipment.
Engineering Limitations & Chemical Fitness Warnings

Extracted directly from Brady Technical Data Sheets to prevent real-world application failures and chemical degradation:

  • Footnote 1 - metal surfaces: The sheet's only numbered footnote reads "Metal surfaces should be labeled at room temperature only." It is printed as the very last line of the "Label applied to room temperature surface" page, directly beneath the ✔ / ◆ / X legend and directly above the "Label applied to cold surface" heading. Scope is not stated: no row, result, or heading in either environmental table carries a superscript "1", and on that same page the marker "1" is already in use in the "NOTE for Surfaces" block to mean the manufacturer VWR International. Do not attach this note to any single row. Note also that the cold-surface table's Freezer row does rate "✔ Stainless steel, aluminum and cardboard storage boxes" - the footnote and that row appear to conflict, and the sheet does not reconcile them.
  • Footnote asterisk - R4300 ribbon and chemical resistance: Attached to "Brady Series R4300 (alternate)*" under RECOMMENDED RIBBONS: "Note: Brady Series R4300 ribbon may be used if chemical resistance is not required with Ethanol, Toluene and Xylene."
  • Testing basis - R6400 ribbon: Under RECOMMENDED RIBBONS: "Please note that testing described in this Technical Data Sheet was performed on materials printed with the Brady Series R6400 ribbon." The chemical resistance section separately states that both the Brady Series R6400 and the Brady Series R4300 ribbons were tested.
  • Regulatory approvals - status not stated on sheet: The REGULATORY APPROVALS section states no compliance status, agency approval, or standards conformance. It gives only a pointer: for information on the Weee-RoHS compliance status for a Brady product, go to one of the following websites. In Canada: www.bradycanada.ca/weee-rohs. In Europe: www.bradyeurope.com/rohs. In Japan: www.brady.co.jp/products/labelsuse/rohs. All other regions: www.bradyid.com/weee-rohs
  • Per-configuration verdicts do not transfer: Results differ between application methods within a single row, so a verdict for one configuration must not be read across to another. Example from "Liquid Nitrogen to boiling water" with the label applied to a room temperature surface: "✔ Polypropylene tube/vial, gapped" but "◆ Polypropylene tube/vial, ⅛" overlapped, longitudinal". Example from "Freezer" with the label applied to a cold surface: "✔ Glass test tube, gapped" but "◆ Glass test tube, longitudinal, ⅛" overlap". Verdicts also differ between the two tables for the same substrate - flat polypropylene is ◆ under Liquid Nitrogen but ✔ under Freezer, in both the room-temperature-surface and cold-surface tables.
  • Configurations rated mixed: Rated ◆ ("Label may work in application; test results were mixed"), by table and row. Label applied to room temperature surface - Liquid Nitrogen: Plastic Whirl-Pak bags, Flat polypropylene. Freezer: Plastic Whirl-Pak bags. Liquid Nitrogen to boiling water: Polypropylene tube/vial ⅛" overlapped longitudinal, Glass microscope slide, Flat polypropylene. Freezer to boiling water: Polypropylene tube/vial longitudinal ⅛" overlap. Label applied to cold surface - Liquid Nitrogen: Flat polypropylene, Plastic Whirl-Pak bags. Freezer: Glass test tube longitudinal ⅛" overlap, Polypropylene tube/vial ⅛" overlap longitudinal, Plastic Whirl-Pak bags. Liquid Nitrogen to boiling water: Glass test tube ⅛" overlap longitudinal, Glass microscope slide, Flat polypropylene. Freezer to boiling water: Glass test tube ⅛" overlap longitudinal. No entry in either environmental table is rated X ("not recommended").
  • 10% Sodium Hydroxide damages the label stock: It is the only reagent whose "EFFECT TO LABEL STOCK" cell reads "Topcoat delaminates from label", and it is the only reagent rated 4 ("severe smear or print removal (print illegible or just barely legible)") in all four printed-image columns - R6400 without rub, R6400 with rub, R4300 without rub, and R4300 with rub.
  • Application condition for best results: Stated in the preamble to both environmental tables: "For best results label should be wrapped around and overlapped on itself by at least ⅛"."
  • User responsibility for fitness for use: Under Shelf Life: "It remains the responsibility of the user to assess the risk of using this product. We encourage customers to develop testing protocols that will qualify a product's fitness for use in their actual application."
  • Data disclaimer - averages not for specification purposes: "All values shown are averages and should not be used for specification purposes." The sheet adds that its test data is for general information only, must not be relied upon for designs and specifications or as meeting specified performance criteria, and that customers wanting specifications or performance criteria for a specific application should contact Brady.
  • Product compliance information disclaimer: Brady states that product compliance information comes from raw-material suppliers or from third-party independent laboratory testing, that Brady makes no independent representations or warranties express or implied, and that Brady assumes no liability in connection with the use of that information.
  • Warranty disclaimer: The WARRANTY section states products are sold on the understanding that buyers will test them in actual use and determine adaptability to their intended uses themselves. Brady's obligation is limited to replacement of product shown to its satisfaction to have been defective at the time of sale, the warranty does not extend to anyone obtaining the product from the buyer, and implied warranties of merchantability and fitness for a particular purpose are expressly excluded.
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ASTM Physical & Mechanical Properties

Standardized laboratory test data measured in accordance with ASTM D 1000, ASTM D 2979, and ASTM D 2671.

Physical PropertyTest MethodStandard Test Units (US)Metric Units (SI)
Total ThicknessASTM D 10003.2 mils (0.003 in)0.081 mm
Adhesion to glass (20 minute dwell)ASTM D 100030 oz/in33 N/100mm
Adhesion to glass (24 hour dwell)ASTM D 100040 oz/in43 N/100mm
Adhesion to polypropylene (20 minute dwell)ASTM D 100012 oz/in13 N/100mm
Adhesion to polypropylene (24 hour dwell)ASTM D 100020 oz/in22 N/100mm
Adhesion to stainless steel (20 minute dwell)ASTM D 100015 oz/in16.6 N/100mm
Adhesion to stainless steel (24 hour dwell)ASTM D 100022 oz/in24.4 N/100mm

Thermal Transfer Ribbon Compatibility

Official Brady recommended ribbons engineered for maximum contrast, smear resistance, and UL certification compliance.

Recommended Thermal Transfer
Series R4300
Series R6400
* Note: Testing print permanence with official Brady ribbons is required to maintain UL/CSA agency certification on printed labels.

Chemical & Solvent Resistance Matrix

Standardized dip and rub immersion test observations across industrial fuels, oils, solvents, and cleaners.

Tested per ASTM D 895 / Brady standard dip & rub immersion.
Chemical Reagent / SolventSubstrate / Adhesive EffectThermal Ribbon Permanence
EthanolNo visible effect
R6400 without rub:1
R6400 with rub:1
R4300 without rub:1
R4300 with rub:2
TolueneSlight edge infiltration or lifting
R6400 without rub:1
R6400 with rub:1
R4300 without rub:1
R4300 with rub:4
IsopropanolSlight edge infiltration or lifting
R6400 without rub:1
R6400 with rub:1
R4300 without rub:1
R4300 with rub:2
XyleneSlight edge infiltration or lifting
R6400 without rub:1
R6400 with rub:1
R4300 without rub:1
R4300 with rub:4
Dimethylsulfoxide (DMSO)No visible effect
R6400 without rub:1
R6400 with rub:1
R4300 without rub:1
R4300 with rub:2
50% Acetic AcidNo visible effect
R6400 without rub:1
R6400 with rub:1
R4300 without rub:1
R4300 with rub:1
10% Sodium HydroxideTopcoat delaminates from label
R6400 without rub:4
R6400 with rub:4
R4300 without rub:4
R4300 with rub:4
10% Chlorox® SolutionNo visible effect
R6400 without rub:1
R6400 with rub:1
R4300 without rub:1
R4300 with rub:1

Environmental & Aging Durability Testing

Environmental Exposure ConditionObservation & Legibility Result
492 Freezerbondz White Polyester Thermal Printable Label Stock - Material Spec (Brady B-492) Material familyB-492
white film with white thermal transfer printable topcoat, permanent acrylic adhesive ## Summary Brady B-492 Freezerbondz is a white polyester thermal transfer label stock with a white printable topcoat and a permanent acrylic adhesive, designed for laboratory identification such as vials, centrifuge tubes, test tubes, straws, and slides. It can be applied to frozen surfaces including glass and polypropylene stored in liquid nitrogen, but the sheet carries a footnote reading "Metal surfaces should be labeled at room temperature only." All testing described on the sheet was performed with the Brady Series R6400 ribbon, and the alternate Brady Series R4300 ribbon may only be used if chemical resistance to Ethanol, Toluene and Xylene is not required. ## Verified specifications - TDS numberB-492
label applied to room temperature surfacePrinted B-492 samples were laminated at room temperature to the surfaces listed and allowed to dwell 24 hours at room temperature prior to exposure. Labels applied with three applications (gapped, overlapped [with ⅛" overlap], longitudinal) to 1.5 mL Eppendorf tubes, 5 mL Cryogenic (polypropylene) vials, 15 mL and 50 mL Polypropylene tubes, 15 mL Glass tubes, wrapped around straws and flat on plastic Whirl-pak bags and boxes
High service temperature - label applied to room temperature surface30 days at various temperatures - Moderate discoloration at 230°F (110°C), no visible effect to print. Severe yellowing at 266°F (130°C), label still functional
label applied to room temperature surface3 cycles of 4 hours at -320°F (-196°C) and 20 hours at room temperature
label applied to room temperature surface3 cycles of 16 hours at -112°F (-80°C) and 8 hours at room temperature
label applied to room temperature surface1 hour at -320°F (-190°C) then placed in boiling water 212°F (100°C) for 10 minutes (the sheet prints -190°C in this row; it prints -196°C alongside -320°F everywhere else)
label applied to room temperature surface1 hour at -112°F (-80°C) then placed in boiling water 212°F (100°C for 10 minutes
492 samples printed with the Brady Series R6400 and the Brady Series R4300 ribbons was tested at room temperature. Printed samples were laminated to aluminum panels and allowed to dwell 24 hours prior to testing. Samples were immersed in test solvents for 15 minutes, then removed and rubbed 10 times with a cotton swab saturated with the test fluid. Column scopethe four numbered columns sit under the heading "EFFECTS TO PRINTED IMAGE" and are split by ribbon. The "Effect to label stock" column sits outside that grouping and is not attributed to either ribbon.

Verified Target Applications & Use Cases

  • Laboratory identification such as vials, centrifuge tubes, test tubes, straws, and slides (stated under APPLICATIONS)
  • Can be applied to frozen surfaces including glass and polypropylene stored in liquid nitrogen (stated under SPECIAL FEATURES)
  • Performs well in common laboratory environments such as liquid nitrogen and freezer applications (stated under SPECIAL FEATURES)

Brady B-492 Frequently Asked Questions & Engineering Guide

Verified technical answers on physical adhesion, temperature thresholds, ribbon pairings, and replacement standards for B-492.

Yes. Brady B-492 FreezerBondz™ polyester utilizes a proprietary cryogenic adhesive capable of adhering directly to frozen and frosted laboratory vials, straw tubes, and microplates at -196°C (-320°F) in liquid nitrogen storage. It also survives boiling water baths (+100°C) and autoclave sterilization without peeling or ink degradation.

Brady B-492 is rated for continuous service temperatures from -196°C to 110°C (-321°F to 230°F). In laboratory heat-aging tests, it maintains dimensional stability and barcode contrast across broad thermal cycles.

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